TECHNOLOGICAL AND DIELECTRIC PROPERTIES OF RESINS FOR DLP 3D PRINTING WITH ADDITIVES OF AL2O3 AND CTS-19 POWDERS
Cite as: A.V. Yudin, Yu.I. Yurasov, O.A. Belyak, P.S. Plyaka, M.I. Tolstunov. Technological and dielectric properties of resins for DLP 3D printing with additives of AL2O3 and CTS-19 powders // Izvestiya SFedU. Engineering Sciences – 2024. – N. 6. - P. 280-291. doi: 10.18522/2311-3103-2024-6-280-291
Abstract
Expanding the range of materials available for processing by additive methods is of great interest to
industry. Technologies such as 3D polymer printing significantly expand the boundaries of design capabilities,
allowing a transition to next-generation devices. In view of the gradual implementation of such approaches
in practice, a new impetus for development has been given to the direction of metamaterials -
volumetric structures whose geometry allows for more complete use of the properties of the base material.
In particular, ceramics, common in modern electronics, can be introduced into a polymer molded by an
additive method as a functional additive. Subsequent heat treatment of such compositions allows obtaining a macrostructured ceramic-polymer or purely ceramic framework with unique piezo- or dielectric properties.
However, additive particles can significantly change the technological properties of the base material,
which must be taken into account. At the same time, isolating the empirical features characterizing this
dynamics is a non-trivial task. Thus, in publications on UV-curable composites, the viscosity criterion of
the composition is recognized as the leading feature. At the same time, optical permittivity, which determines
the required equipment power, is not considered properly. In this regard, the presented work studies
the viscosity, dielectric, optical and temperature properties of composites based on UV-curable resin for
DLP 3D printing, containing additives of 5 vol. % Al2O3 and CTS-19 powders. A method for qualitative
express analysis of the technological suitability of the composition based on the Scotch test is presented. It
is shown that the viscosity of the composition is less significant in comparison with its optical permittivity
in the UV range. The considered compositions have temperature stability up to 300 ⁰С. The introduction of
powder additives makes it possible to increase the dielectric permittivity ε'/ε0 by 2.5 times and reduce
dielectric losses in the material when heated above 110 ⁰C. It is shown that composites containing aluminum
oxide have potential for use in electronics
References
2021, 209, 110008.
2. Young-Geun Park et al. High-Resolution 3D Printing for Electronics, Advanced Science, 2022, 9,
2104623.
3. Marcin Ziółkowski and Tomasz Dyl. Possible Applications of Additive Manufacturing Technologies in
Shipbuilding: A Review, Machines, 2020, 8, 84.
4. Cheng Sun et al. Additive Manufacturing for Energy: A Review, Applied Energy, 2021, 282 A,
116041.
5. Henry A. Colorado et al. Additive manufacturing in armor and military applications: research, materials,
processing technologies, perspectives, and challenges, Journal of Materials Research and Technology,
2023, 27, pp. 3900-3913.
6. Iftekar S.F. et al. Advancements and Limitations in 3D Printing Materials and Technologies: A Critical
Review, Polymers, 2023, 15, 2519.
7. Chuhong Zhang et al. Current advances and future perspectives of additive manufacturing for functional
polymeric materials and devices, SusMat, 2021, 1, pp. 127-147.
8. Amit M.E. Arefin et al. Polymer 3D Printing Review: Materials, Process, and Design Strategies for
Medical Applications, Polymers, 2021, 13, 1499.
9. Erin M. Maines et al. Sustainable Advances in SLA/DLP 3D Printing Materials and Processes, Green
Chemistry, 2021, 18.
10. Xu X. et al. Vat photopolymerization 3D printing for advanced drug delivery and medical device applications,
Journal of Controlled Release, 2020.
11. Thomas Lacelle et al. Additive manufacturing of polymer derived ceramics: Materials, methods, and
applications, APL Materials, 2023, 11, 070602.
12. Aamer Nazir et al. Multi-material additive manufacturing: A systematic review of design, properties,
applications, challenges, and 3D printing of materials and cellular metamaterials, Materials & Design,
2023, 226, 111661.
13. Ren Z., Mujib S.B., Singh G. High-Temperature Properties and Applications of Si-Based Polymer-
Derived Ceramics: A Review, Materials, 2021, 14, 614.
14. Suresh Kumar N. et al. A Review on Metamaterials for Device Applications, Crystals, 2021, 11, 518.
15. Mamatha S., Biswas P., Johnson R. Digital light processing of ceramics: an overview on process, materials
and challenges, Progress in Additive Manufacturing, 2023, 8, pp. 1083-1102.
16. Truxova V. et al. Ceramic 3d printing: Comparison of SLA and DLP technologies, MM Science Journal,
2020, 2, pp. 3905-3911.
17. Peng Cai et al. Effects of slurry mixing methods and solid loading on 3D printed silica glass parts
based on DLP stereolithography, Ceramics International, 2020, 46. 10. B, pp. 16833-16841.
18. Komissarenko D. et al. DLP 3D printing of scandia-stabilized zirconia ceramics, Journal of the European
Ceramic Society, 2021, 41. 1, pp. 684-690.
19. Xiaohong Xu et al. Study of alumina ceramic parts fabricated via DLP stereolithography using powders
with different sizes and morphologies, Applied Ceramic Technology, 2022, 20. 2.
20. Rytis Mitkus et al. Investigation and attempt to 3D print piezoelectric 0-3 composites made of photopolymer
resins and PZT, Proceedings of the ASME 2020 Conference on Smart Materials, Adaptive
Structures and Intelligent Systems. 2020. September 14-16. Irvine. CA. USA.
21. Sotov A. et al. LCD-SLA 3D printing of BaTiO3 piezoelectric ceramics, Ceramics International,
2021, 47, pp. 30358-30366.
22. Yushun Zeng et al. 3D-Printing Piezoelectric Composite with Honeycomb Structure for Ultrasonic
Devices, Micromachines, 2020, 11, 713.
23. Qiaolei Li et al. Balancing flexural strength and porosity in DLP-3D printing Al2O3 cores for hollow
turbine blades, Journal of Materials Science & Technology, 2022, 104, pp. 19-32.
24. Melentiev R. et al. Metallization of polymers and composites: State-of-the-art approaches, Materials &
Design, 2022, 221, 110958.
25. Rodrigues S. et al. Improvement of the fatigue and the ferroelectric properties of PZT films through a
LSCO seed layer, Materials Science and Engineering, 2013, B. 178, pp. 1224-1229.
26. Hameed M. et al. Preparation and Characterization of Al2O3 Nanostructures by Pulsed-Laser Deposition,
Journal of Optoelectronics and Photonics, 2015, 6. 8, pp. 43-46.
27. Rouholah Ashiri et al. Development and investigation of novel nanoparticle embedded solutions with
enhanced optical transparency, Journal of Materials Research, 2014, 29 (24), pp. 2949-2956.
28. Yurasov Yu.I. Patent RF na poleznuyu model' № 66552. Avtomaticheskiy izmeritel'nyy stend
elektrofizicheskikh parametrov segneto-p'ezomaterialov v shirokom intervale temperatur i chastot
[Russian Federation Patent for Utility Model No. 66552. Automatic Measuring Stand for
Electrophysical Parameters of Ferroelectric-Piezoelectric Materials in a Wide Range of Temperatures
and Frequencies]. Application No. 2007102548, priority from 23.01.2007. Reg. 10.09.2007. Published
10.09.2007. Bulletin of Inventions. Utility Models No. 25, 2007.
29. Yurasov Yu.I. Svidetel'stvo ob ofitsial'noy registratsii programmy dlya EVM. №2006611142. Raschet
dielektricheskoy pronitsaemosti i tangensa ugla dielektricheskikh poter' v shirokom intervale
temperatur i chastot (Laboratornyy stend YuKOMP 2.0) [Certificate of official registration of the
computer program. No. 2006611142. Calculation of permittivity and tangent of dielectric loss angle in
a wide range of temperatures and frequencies (Laboratory stand YuKOMP 2.0)]. Registered in the
Register of computer programs on March 29, 2006.
30. Reznichenko L.A., Andryushin K.P., Andryushina I.N., Verbenko I.A., Kubrin S.P., Pavelko A.A.,
Pavlenko A.V., Yurasov Yu.I. Attestat № 184 ot 03.05. 2011. Metodika № GSSSD ME 184-2011 FGUP
«Standartinform» GNMTS «SSD». Metodika eksperimental'nogo opredeleniya kompleksnoy
dielektricheskoy pronitsaemosti, tangensa ugla dielektricheskikh poter', temperatury Kyuri
dielektricheskikh materialov v shirokom diapazone temperatur (10÷1000) K, chastot (10-3÷1٠106) Gts
elektricheskogo izmeritel'nogo polya [Certificate No. 184 dated 03.05. 2011. Methodology No. GSSSD
ME 184-2011 FSUE "Standartinform" GNMC "SSD". Methodology for experimental determination of
complex permittivity, dielectric loss tangent, Curie temperature of dielectric materials in a wide range of
temperatures (10÷1000) K, frequencies (10-3÷1٠106) Hz of the electric measuring field].
31. Yurasov Y.I. and Nazarenko A.V. Parameter of dielectric loss distribution in the new model for complex
conductivity based on Havriliak–Negami formula, J. of Advanced Dielectrics, 2020, 10 (1,2),
2060006.
